马猛涛 教 授

2023.07 – 至     今       教   授，博导，科技处副处长，南京林业大学

2018.06 – 2023.06      教   授，博导，理学院副院长，南京林业大学

2012.03 – 2018.06      副教授，博导，化学系副系主任，南京林业大学

2010.10 – 2012.02      博士后，莫纳什大学(Monash University, 澳大利亚八大名校之一)

2009.12 – 2010.10      博士后，新加坡国立大学(NUS)，新加坡

2005.07 – 2009.12      博   士，新加坡南洋理工大学(NTU)，新加坡

2002.09 – 2005.06      硕   士，苏州大学

1998.09 – 2002.06      本   科，南京师范大学

研究方向：绿色化学，低价态（一价）主族金属化合物的合成与催化应用，金属有机化学，有机催化，绿色催化在林源天然产物中的应用等

[90] Catalyst-free Electrochemical Sulfonylation of Organoboronic Acids,  J. Org. Chem. 2023, 88, 2296.

[89] Metallic and dimensional optimization of metal-organic frameworks for high-performance lithium-sulfur batteries, Chem. Eur. J. 2023, e202300407. 

[88] Magnesium halide-catalyzed hydroboration of isocyanates and ketones, Org. Biomol. Chem. 2023, DOI: 10.1039/D3OB00531C. 

[87] Catalyst-free and solvent-free hydroboration of alkynes and alkenes with catecholborane, Chin. J. Org. Chem. 2023, doi: 10.6023/cjoc202209011.

[86] Catalyst-free green synthesis of phthalazinones at room temperature, Heterocycles 2023, 106, 136.

[85] Highly Specific Antibiotic Detection on Water-Stable Black Phosphorus Field-Effect Transistors, ACS Sens. 2023, 8, 858.

[84] Nickel-Catalyzed Direct Cross-Coupling of Aryl Thioether with Aryl Bromide, Org. Lett. 2023, 25, 1771.

[83]  Calcium-Catalyzed Hydroboration of Alkenes, ACS Sustainable Chem. Eng. 2022, 10, 5015.

[82]  Electrochemical hydroboration of carbonyl compounds, Dalton Trans. 2022, 51,11868.

[81] One-Pot Synthesis of 2,3-Disubstituted Indanone Derivatives in Water under Exogenous Ligand-Free and Mild Conditions, J. Org. Chem. 2022, 87, 7884.

[80] Chemoselective electrocatalytic hydroboration of alkynes with pinacolborane,  J. Mol. Struct. 2022, 1266, 133463.

[79] Electrochemical flfluorosulfonylation of alkenes to access vicinal fluorinated sulfones derivatives, Tetrahedron 2022, 106, 132651.

[78] Four-component defluorinative reaction of allylic fluorides, amidines, and Cs₂CO₃ under transitionmetal-free conditions, Green Chem. 2022, 24, 6816.

[77] HP(O)Ph2/H2O-promoted hydrodeflfluorination of triflfluoromethyl alkenes, Green Chem. 2022, 24, 2777.

[76] Dual Role of (NH₄)₂CO₃ Enables Defluorinative Synthesis of β‑Fluoroalkylated Aminovinyl Ketones, Org. Lett. 2022, 24, 9086.

[75] Transition-metal-free hydroamination/defluorination/cyclization of perfluoroalkyl alkynes with amidines, Org. Chem. Front. 2022, 9, 109.

[74] DMSO-Promoted Difluoroalkylation of Organophosphonium Salts with Difluoroenol Silyl Ethers, Org. Lett. 2022, 24, 5557.

[73] Palladium-Catalyzed Sonogashira Coupling of a Heterocyclic Phosphonium Salt with a Terminal Alkyne, Org. Lett. 2022, 24, 4919.

[72]  Nickel-Catalyzed Direct Cross-Coupling of Diaryl Sulfoxide with Aryl Bromide, J. Org. Chem. 2022, 87, 11899.

[71] Difluorinated Silyl Enol Ethers as Fluorine-Containing Building Blocks for the Synthesis of Organofluorine Compounds, Chin. J. Org. Chem. 2022, 42, 3562.

[70]  Manipulating K‑Storage Mechanism of Soft Carbon via Molecular Design-Driven Structure Transformation, ACS Appl. Mater. Interfaces 2022, 14, 54698.

[69] Electrolyte Regulation for Non-Graphitic Carbon to Achieve Stable Long-Cycling K‑Storage, ACS Appl. Mater. Interfaces 2022, 14, 44479.

[68] Research progress in anode materials based on multiple potassium storage mechanisms, Sustain. Mater. Techno. 2022, 33, e00480.

[67] Palladium-Catalyzed Synthesis of Esters from Arenes through C−H Thianthrenation, Org. Lett. 2022, 24, 6031.

[66] Palladium-Catalyzed Synthesis of C‑1 Deuterated Aldehydes from (Hetero) Arenes Mediated by C(sp²)−H Thianthrenation, Org. Lett. 2022, 24, 5608.

[65] Synthesis of β‑Polychlorinated Alkynes Enabled by Copper Catalyzed Multicomponent Reaction, Org. Lett. 2022, 24, 4772.

[64] Copper-catalysed synthesis of triflfluoromethyl allenes via flfluoro-carboalkynylation of alkenes, Org. Chem. Front. 2022, 9, 1844.

[63] Zhuangzhi Shi, Photoinduced Etherification of Less-Strained Cycloketoxime Esters Enabled by C-C Bond Cleavage, J. Org. Chem. 2022, 87, 3577.

[62] SOMOphilic Alkynylation of Unreactive Alkenes Enabled by Iron-Catalyzed Hydrogen Atom Transfer, Molecules 2022, 27, 33.

[61]  Synthesis of functionalized malononitriles via Fe-catalysed hydrogen atom transfers of alkenes, Org. Biomol. Chem. 2022, 20, 1480.

[60] ZnBr₂‑Catalyzed Dehydrogenative Borylation of Terminal Alkynes, J. Org. Chem. 2021, 86, 16666.

[59]  Recent advances on the bacterial cellulose-derived carbon aerogels, J. Mater. Chem. C 2021, 9, 818.

[58] Green and up-scalable fabrication of superior anodes for lithium storage based on biomass bacterial cellulose, Adv. Powder Technol. 2021, 32, 2484.

[57] Synthesis of Zn-Li Bimetallic Complex and Its Catalytic Application in Hydroboration of Isocyanate, Chin. J. Org. Chem. 2021, 41, 357.

[56] Nickel-Catalyzed Diastereoselective Reductive Cross-Coupling of Disubstituted Cycloalkyl Iodides with Aryl Iodides, Org. Lett. 2021, 23, 5118.

[55] Titanium(IV)-Mediated Ring-Opening/Dehydroxylative Cross-Coupling of Diaryl-Substituted Methanols with Cyclopropanol Derivatives, J. Org. Chem. 2021, 86, 15753.

[54] Three-Component Bisannulation for the Synthesis of Trifluoromethylated Tetracyclic Aza-Aromatics through Six C(sp³)-F Bond Cleavage and Four C-N Bond Formation, J. Org. Chem. 2021, 86, 8236.

[53] Copper-catalyzed regio- and stereoselective fluorocarboalkynylation of alkynes,Org. Chem. Front. 2021, 8, 6857.

[52]  Copper-catalyzed Beckmann-type fragmentation of less-strained cycloketoxime esters, Org. Chem. Front. 2021, 8, 2985.

[51] Honeycomb-like 2D metal-organic polyhedral framework exhibiting selectively adsorption of CO₂, J. Solid State Chem. 2021, 300, 122230.

[50]  Syntheses of asymmetrical magnesium(I) complexes and their catalytic application in epoxide hydroboration, Org. Chem. Front., 2020,7,3625.

[49] Magnesium-catalyzed hydroboration of organic carbonates, carbon dioxide and esters, Dalton Trans., 2020, 49, 2776. 

[48] Grignard reagents-catalyzed hydroboration of aldehydes and ketones, Tetrahedron, 2020, 76, 131145.

[47] Efficient Magnesium-Catalyzed Hydroboration of Carboxylic Acids, Chin. J. Org. Chem. 2020, 40, 2086.

[46] Recent advances in alkaline earth metal catalyzed hydroboration reactions, Sci Sin Chim, 2020, 50, 2020, 50, 639.

[45] Catalyst-free and Solvent-free Cyanosilylation and Knoevenagel Condensation of Aldehydes,ACS Sustainable Chem. Eng., 2019, 7, 1718.

[44] Catalyst-free and solvent-free hydroboration of Ketones, New J. Chem., 2019, 43, 10744.

[43] Green hydroboration of carboxylic acids and mechanism investigation, Org. Biomol. Chem., 2019, 17, 3604.

[42]   Palladacycle promoted asymmetric hydrophosphination of a,β-unsaturated sulfonyl fluorides, J. Organomet. Chem. 2019, 899, 120912.

[41] Unsymmetrical β-diketiminate magnesium(I) complexes: syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compounds,Org. Chem. Front., 2018, 5, 3538.

[40] Low-valent magnesium(I)-catalyzed cyanosilylation of ketones,Chem. Commun.2018, 54,3042.

[39] Ytterbium-Catalyzed Hydroboration of Aldehydes and Ketones, J. Org. Chem.2018, 83, 69.

[38]  Efficient and selective aldehyde cyanosilylation catalyzed by Mg-Li bimetallic complex,J. Organomet. Chem.2018, 874, 83.

[37] Efficient and selective carbonyl hydroboration catalyzed by a lithium NCN-Pincer magnesiate complex [Li(THF)4][NCN-MgBr2],J. Organomet. Chem. 2018, 868, 31.

[36] A novel fluorescence turn off-on nano-sensor for detecting Cu2+ and Cysteine in living cells, J. Photoch. Photobio.A 2018, 362, 14.

[35] Quercetin-coated Fe3O4 nanoparticle sensors based on low-field NMR for determination and removal of Pb2+ and Cu2+ in biological samples, Anal. Methods 2018, 10, 2494.

[34] High anticancer potency on tumor cells of dehydroabietylamine Schiff-base derivatives and a copper(II) complex, Eur. J. Inorg. Chem. 2018, 146, 451.

[33]  Sterically bulky amido magnesium methyl complexes: syntheses, structures and catalysis, RSC Advances 2017, 7, 45401.

[32] Syntheses of sterically bulky schiff-base magnesium complexes and their application in the hydrosilylation of ketones, Eur. J. Inorg. Chem. 2016, 5057. 

[31]  Sterically bulky β-diketiminate magnesium complexes: syntheses, crystal structure and catalytic hydrosilylation, Chin. J. Inorg. Chem. 2016, 10, 1857. 

[30] Metal effects on the asymmetric syntheses of chiral P-N bidentate ligands,J. Organomet. Chem. 2016, 824, 99.

[29] Synthesis of magnesium(I) complexes and their applications, Chin. J. Org. Chem. 2016, 36, 72.

[28] Asymmetric Diels-Alder reaction between 3,4-dimethyl-1-phenylphosphole and (Z/E)-diphenyl-1-styrylphosphine,J. Organomet. Chem.2016, 806, 1.

[27] Palladacyclo-promoted asymmetric hydrophosphination reaction between diphenylphosphine and 2-ethynylpyridine, J. Organomet. Chem. 2016, 801, 1.

[26] High Gas adsorption Capacity of an agw-type Metal-organic Framework Decorated with Methyl Groups, Eur. J. Inorg. Chem. 2016, 29, 4727. 

[25] Synthesis and structural characterization of amine-bridged bis(phenolate) lanthanide complexes, J. Organomet. Chem. 2015, 787, 51. 

[24]  Metal effects on the asymmetric cycloaddition reaction between 3,4-dimethyl-1-phenylphosphole and sulfoxide, Organometallics 2015, 34, 5081.

[23] A porous cobalt-based MOF with high CO2 selectivity and uptake capacity, RSC Advances 2015, 5, 29505. 

[22]  Gold-catalyzed tandem reactions of 2-alkynyl arylazides and carboxylic acids for synthesis of 1H-indol-3-yl esters, Chin. J. Org. Chem. 2015, 35, 1469. 

[21] Palladium-promoted asymmetric cycloaddition reaction of arsole via aunusual exo-endo stereochemically controlled method, J. Organomet. Chem. 2014, 756, 34.

[20] Asymmetric synthesis of a chiral diarsine ligand via a cycloaddition reaction between 3,4-dimethyl-1-phenylarsole and diphenylvinylarsine, Tetrahedron: Asymmetry 2014, 25, 1100.

[19] Platinum Complexes Containing Pyramidalized Germanium and Tin Dihalide Ligands Bound through σ,σ M=E Multiple Bonds, Chem. Eur. J. 2014, 20, 16888. 

[18] Metal-Only Lewis Pairs Featuring Unsupported Pt→M (M = Zn or Cd) Dative Bonds, Chem. Commun. 2013,49,48.

[17]  Magnesium(I) Dimer as Reagents for the Reductive Coupling of Isonitriles and Nitriles, Chem. Eur. J. 2012,18,10669.

[16]  Chiral cyclopalladated complex promoted asymmetric synthesis of diester-substituted P,N-ligands via stepwise hydrophosphination and hydroamination reactions, Dalton Trans. 2012,41,5391.

[15]  Steric Effects on Control of Endo/Exo-Selectivity in Asymmetric Cycloaddition Reaction of 3,4-Dimethyl-1-phenylarsole, Dalton Trans. 2010, 39, 5453.

[14]  Metal Effects on the Asymmetric Synthesis of a New Chiral As-P=S Ligand, Eur. J. Inorg. Chem. 2010, 12, 1865. 

[13] Controlled synthesis of lanthanide-lithium inverse crown ether complexes, Inorg. Chem. Commun. 2010, 13, 1566.

[12]  Metal Effects on the Asymmetric Cycloaddition Reaction between 3,4-Dimethyl-1-phenylarsole and Diphenylvinylphosphine Oxide, Organometallics 2009, 28, 4886. 

[11] Template Effects on the Asymmetric Cycloaddition Reaction between 3,4-Dimethyl-1-phenylarsole and Diphenylvinylphosphine and Their Arsenic Elimination Reaction, J. Organomet. Chem. 2009, 694, 1929. 

[10] Asymmetric Synthesis of Functionalized 1,2-Diphosphine via the Chemoselective Hydrophosphination of Coordinated Allylic Phosphines, Organometallics 2009, 28, 780.

[9]  Asymmetric Synthesis of a Chiral Hetero-bidentate As-P Ligand Containing both As and P-Stereogenic Centres, J. Organomet. Chem. 2008, 693, 3289. 

[8]  Novel Stereochemistry, Reactivity, and Stability of an Arsenic Heterocycle in a Metal-Promoted Asymmetric Cycloaddition Reaction, Inorg. Chem. 2007, 46, 9488. 

[7] Synthesis and Characterization of Amine Bis(phenolate) Lanthanide Chlorides, J. Ningbo University 2007, 20, 368.

[6] Asymmetric synthesis of a P-chiral heteroditopic P-P=S ligand via chiral metal template promoted cycloaddition between 3,4-dimethyl-1-phenylphosphole and its sulfonated analog, J. Organomet. Chem. 2006, 691, 3083.

[5] Synthesis and crystal structure of amine bis(phenolate) ytterbium potassium bimetallic complex, Chem. J. Inter. 2005, 7, 36.

[4]  Carbon-bridged biphenolate lanthanide complexes: synthesis and their catalytic activity for the Diels–Alder reaction, J. Mol. Struct. 2005, 743, 163.

[3] Synthesis, Characterisation of Carbon-Bridged (Diphenolato)lanthanide Complexes and Their Catalytic Activity for Diels–Alder Reactions, Eur. J. Inorg. Chem. 2005, 676.

[2]  Synthesis and X-ray Crystal Structures of Amine Bis(phenolate) Lanthanide Complexes Containing Alkali Metal Cation, J. Mol. Struct. 2005, 740, 69. 

[1]  Synthesis, Reactivity, and Characterization of Amine Bis(phenolate) Lanthanide Complexes and Their Application in the Polymerization of ε-Caprolactone, Organometallics 2005, 24, 4014.

1.国家自然科学基金面上项目：低价态（一价）钙金属化合物的制备及其催化性能的研究, 2022-2025，主持。

2.国家自然科学基金面上项目：不对称一价镁金属化合物的合成及其催化性能的研究, 2018-2021，主持。

3.国家自然科学基金面上项目：低价态（一价）稀土化合物的合成及反应性能的研究, 2014-2017,主持。

4.江苏省自然科学基金面上项目:氨基和膦亚胺稳定的低价镁金属化合物的合成及应用, 2014-2017,主持。

5.留学人员科技活动项目择优资助基金，2013-2015,主持。

6.江苏省有机合成重点实验室开放课题基金，2013-2015,主持。

7.南京林业大学高层次人才引进科研基金，2013-2015,主持。

8.南京林业大学标志性成果培育建设项目，2019-2021,主持。

9.2014年度江苏省高校“青蓝工程”优秀青年骨干教师。

10.2022年江苏省第六期“333高层次人才培养工程”第三层次培养对象

11.江苏中烟工业有限责任公司合作科技项目，2022-2025。

催化导论，有机化学等